Synthesis of mesoporous composite materials of nitrogen-doped carbon and silica using a reactive surfactant approach

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Mesoporous composite materials of nitrogen-doped carbon and silica were synthesised in a one-step-process applying a soft templating procedure. The template used in the sol–gel synthesis of the silica is a cationic surfactant with distinct reactivity to form nitrogen-doped graphitic carbon upon heating. This reactivity is derived from the combination of the dicyanamide anion with a nitrogen-containing pyridinium cation, as it is known from ionic liquids used as nitrogen-doped carbon precursors. Thus applying this surfactant in a conventional sol–gel synthesis yields a silica gel doped with a precursor for N-doped carbon. By subsequent annealing mesoporous composite materials of silica and nitrogen-doped carbon are obtained

Nitrogen- and phosphorus-co-doped carbons with tunable enhanced surface areas promoted by the doping additives

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.1-Butyl-3-methyl-pyridinium-dicyanamide (BMP-dca) is carbonised with tetra-alkyl-phosphonium-bromide additives yielding nitrogen- and phosphorus-co-doped carbons with enhanced BET surface areas promoted by the additives.DFG, EXC 314, Unifying Concepts in Catalysi

Data-free Black-box Attack based on Diffusion Model

Since the training data for the target model in a data-free black-box attack is not available, most recent schemes utilize GANs to generate data for training substitute model. However, these GANs-based schemes suffer from low training efficiency as the generator needs to be retrained for each target model during the substitute training process, as well as low generation quality. To overcome these limitations, we consider utilizing the diffusion model to generate data, and propose a data-free black-box attack scheme based on diffusion model to improve the efficiency and accuracy of substitute training. Despite the data generated by the diffusion model exhibits high quality, it presents diverse domain distributions and contains many samples that do not meet the discriminative criteria of the target model. To further facilitate the diffusion model to generate data suitable for the target model, we propose a Latent Code Augmentation (LCA) method to guide the diffusion model in generating data. With the guidance of LCA, the data generated by the diffusion model not only meets the discriminative criteria of the target model but also exhibits high diversity. By utilizing this data, it is possible to train substitute model that closely resemble the target model more efficiently. Extensive experiments demonstrate that our LCA achieves higher attack success rates and requires fewer query budgets compared to GANs-based schemes for different target models

A Transferable Intersection Reconstruction Network for Traffic Speed Prediction

Traffic speed prediction is the key to many valuable applications, and it is also a challenging task because of its various influencing factors. Recent work attempts to obtain more information through various hybrid models, thereby improving the prediction accuracy. However, the spatial information acquisition schemes of these methods have two-level differentiation problems. Either the modeling is simple but contains little spatial information, or the modeling is complete but lacks flexibility. In order to introduce more spatial information on the basis of ensuring flexibility, this paper proposes IRNet (Transferable Intersection Reconstruction Network). First, this paper reconstructs the intersection into a virtual intersection with the same structure, which simplifies the topology of the road network. Then, the spatial information is subdivided into intersection information and sequence information of traffic flow direction, and spatiotemporal features are obtained through various models. Third, a self-attention mechanism is used to fuse spatiotemporal features for prediction. In the comparison experiment with the baseline, not only the prediction effect, but also the transfer performance has obvious advantages.Comment: 14 pages, 12 figure

Spatial-Temporal Feature Extraction and Evaluation Network for Citywide Traffic Condition Prediction

Traffic prediction plays an important role in the realization of traffic control and scheduling tasks in intelligent transportation systems. With the diversification of data sources, reasonably using rich traffic data to model the complex spatial-temporal dependence and nonlinear characteristics in traffic flow are the key challenge for intelligent transportation system. In addition, clearly evaluating the importance of spatial-temporal features extracted from different data becomes a challenge. A Double Layer - Spatial Temporal Feature Extraction and Evaluation (DL-STFEE) model is proposed. The lower layer of DL-STFEE is spatial-temporal feature extraction layer. The spatial and temporal features in traffic data are extracted by multi-graph graph convolution and attention mechanism, and different combinations of spatial and temporal features are generated. The upper layer of DL-STFEE is the spatial-temporal feature evaluation layer. Through the attention score matrix generated by the high-dimensional self-attention mechanism, the spatial-temporal features combinations are fused and evaluated, so as to get the impact of different combinations on prediction effect. Three sets of experiments are performed on actual traffic datasets to show that DL-STFEE can effectively capture the spatial-temporal features and evaluate the importance of different spatial-temporal feature combinations.Comment: 39 pages, 14 figures, 5 table

Progress and summary of reinforcement learning on energy management of MPS-EV

The high emission and low energy efficiency caused by internal combustion engines (ICE) have become unacceptable under environmental regulations and the energy crisis. As a promising alternative solution, multi-power source electric vehicles (MPS-EVs) introduce different clean energy systems to improve powertrain efficiency. The energy management strategy (EMS) is a critical technology for MPS-EVs to maximize efficiency, fuel economy, and range. Reinforcement learning (RL) has become an effective methodology for the development of EMS. RL has received continuous attention and research, but there is still a lack of systematic analysis of the design elements of RL-based EMS. To this end, this paper presents an in-depth analysis of the current research on RL-based EMS (RL-EMS) and summarizes the design elements of RL-based EMS. This paper first summarizes the previous applications of RL in EMS from five aspects: algorithm, perception scheme, decision scheme, reward function, and innovative training method. The contribution of advanced algorithms to the training effect is shown, the perception and control schemes in the literature are analyzed in detail, different reward function settings are classified, and innovative training methods with their roles are elaborated. Finally, by comparing the development routes of RL and RL-EMS, this paper identifies the gap between advanced RL solutions and existing RL-EMS. Finally, this paper suggests potential development directions for implementing advanced artificial intelligence (AI) solutions in EMS

The exceptional sediment load of fine-grained dispersal systems: Example of the Yellow River, China

Sedimentary dispersal systems with fine-grained beds are common, yet the physics of sediment movement within them remains poorly constrained. We analyze sediment transport data for the best-documented, fine-grained river worldwide, the Huanghe (Yellow River) of China, where sediment flux is underpredicted by an order of magnitude according to well-accepted sediment transport relations. Our theoretical framework, bolstered by field observations, demonstrates that the Huanghe tends toward upper-stage plane bed, yielding minimal form drag, thus markedly enhancing sediment transport efficiency. We present a sediment transport formulation applicable to all river systems with silt to coarse-sand beds. This formulation demonstrates a remarkably sensitive dependence on grain size within a certain narrow range and therefore has special relevance to silt-sand fluvial systems, particularly those affected by dams